金属氧化物中的缺陷化学

Preface1.Introduction Reference2.A Few Useful Cryst0al Structures Introduction Close-Packed Structures Structures for Einght-Coordinate Cations Structures for Ternary Compounds Conclusion References Pnoblems3.Lattice Defects and the Law of Mass Action Introduction Lattice Defects as Part of the Equilibrium State The Law of Mass Action

Preface1.Introduction Reference2.A Few Useful Cryst0al Structures Introduction Close-Packed Structures Structures for Einght-Coordinate Cations Structures for Ternary Compounds Conclusion References Pnoblems3.Lattice Defects and the Law of Mass Action Introduction Lattice Defects as Part of the Equilibrium State The Law of Mass Action Anoter View of Mass Actiom Lattice Disorder in Elemental Solids Summary References4.Intrinsic Ionic Disorder Lattice Defects and Reference States onservation Rules Defect Notation Major Types of Intrinsic Ionic Disorder General Comments on Intrinsic Ionic Disorder References Problems5.Extrinsic Ionic Disorder Introduction The AgCl-CdCls System The CaF2CaO System The TiO2-Nb2O5System Summary of Important Points Schematic Representation of Defect Concentrations Sunmmary of Extrinsic Ionic Disorder References Problems6.Defect Complexes and Associates Introducation Complexes Containing an Impurity Center and an Ionic Defect Intrinsic Ionic Defect Associates The Effect of Impurities on the COncentrations of Defect COmplexes and Associates REferences7.Ionic Transport Introduction Basic Concepts of Diffusion Ionic Conducation in Crystalline Solids Intrinsic and Extrinsic Ionic Conduction Fast Ion Conductors Referencess8.Intrinsic Electronic Disorder Introduction The Development of Energy Bands The Mass-Action Approach The Fermi Function Holes Waves and Effective Masses Electronic Conductivity Hopping Mechanisms The Band Structure of Compounds Chemistry and the Band Gap Summary References9.Extrinsic Electronic Disorder10.Intrnsic Nonstoichiometry11.Extrinsic Nonstoichiometry12.Titanium Dioxide13.Cobalt Oxide and Nickel Oxide14.Barium Titanate15.Order versus DisorderIndex

本书是唯一一本介绍固体无机化合物尤其是金属氧化物化学平衡的著作。对没有多少缺陷化学背景的学生而言，本书解释了如何应用基本原理以及如何解释材料的相关行为。本书讨论的主题包括晶格和电子缺陷、掺杂效应、非化学计量性以及质量与电荷的输运，特别强调了成分元素的一般化学性能与它们的化合物的缺陷化学和输运性能之间的关系。本书覆盖了缺陷形成种类、掺杂效应、化学计量的偏离程度和方向、受主和施主浓度以及其他主题。最后一章对二氧化钛、氧化钴和氧化镍以及钛酸钡这三个体系做了最新的介绍和详细的分析。本书是同类出版物中唯一一本为学生设计了习题的教材。它可满足材料科学与工程、化学和地球化学等学科中不同课程的需要，同时也可以作为研究人员和教师的有益的参考书。