无机化学

Ⅰ Inorganic Chemistry1

Chapter 1 Introduction2

1.1 Observations and Conclusions3

1.2 The Scientific Method3

1.3 Units of Measurement5

1.4 Advice on Studying Chemistry8

Key Words8

Chapter 2 Structures of Atoms9

2.1 Particles in Atoms10

2.2 The Bohr Model12

2.3 The Wave Theory of Electrons13

2.4 Heisenbergs Uncertainty Principle14

2.5 The Schrdinger Equation14

2.6 Quantum Numbers15

2.7 Shapes of Atomic Orbitals17

2.8 ManyElectron Atoms19

2.9 Valence Electrons24

2.10 The Periodic Table and Electronic Configurations of Atoms24

2.11 The Periodicity of the Properties of Elements and Atomic Structure26

Key Words30

Exercises31

Chapter 3 Chemical bonds33

3.1 Ionic Bonds33

3.2 Covalent Bonds35

3.3 Lewis Dot Symbols and Lewis Structure37

3.4 Sigma and Pi Bonds43

3.5 Bond Polarity44

3.6 Bond Energy, Bond Length and Bond Angle45

3.7 Molecular Geometry47

3.8 The VSEPR Model47

3.9 Hybrid Orbitals51

3.10 Molecular Orbitals56

3.11 Intermolecular Force64

Key Words71

Exercises71

Chapter 4 Thermochemistry74

4.1 First Law of Thermodynamics74

4.2 Enthalpy and Enthalpy Change75

4.3 Hesss Law76

4.4 Entropy and the Second Law of Thermodynamics 79

4.5 Spontaneous Processes and Gibbs Free Energy80

4.6 Temperature and Direction of Spontaneous Change81

4.7 Standard Free Energy of Formation and Standard Free Energy of Reaction82

Key Words83

Exercises83

Chapter 5 Chemical Kinetics85

5.1 Reaction Rates85

5.2 Theories of Reaction Rates 87

5.3 Effect of Concentration on Rate of Reaction89

5.4 Rate and Temperature92

5.5 Catalysis94

Key Words95

Exercises96

Chapter 6 Chemical Equilibrium98

6.1 Concept of Equilibrium98

6.2 Equilibrium Constant98

6.3 Le Chteliers Principle103

Key Words106

Exercises106

Chapter 7 Solutions108

7.1 Ways of Expressing Concentration108

7.2 Colligative Properties113

Key Words124

Exercises125

Chapter 8 Solubility Equilibrium127

8.1 Saturated Solutions and Solubility127

8.2 Solubility Equilibria127

8.3 Factors Affecting Solubility130

8.4 Predicting Precipitation Reaction132

8.5 Selective Precipitation134

8.6 Application of Precipitate on Medicine137

Key Words138

Exercises139

Chapter 9 AcidBase Equilibria141

9.1 Acids and Bases141

9.2 Ion Product of Water143

9.3 Strength of Weak Acids and Bases144

9.4 The pH of Weak Acids and Bases146

9.5 The CommonIon Effect148

9.6 Buffer Solutions150

Key Words153

Exercises153

Chapter 10 An Introduction to Electrochemistry155

10.1 OxidationReduction Reactions155

10.2 Balancing OxidationReduction Equations158

10.3 Voltaic Cells161

10.4 Standard Cell Electromotive Force164

10.5 Electrochemistry and Thermodynamics171

10.6 Effect of Concentration on Cell EMF172

10.7 Reduction Potential Diagrams of Elements（Latimer Diagrams）174

Key Words177

Exercises177

Chapter 11 Chemistry of Coordination Compounds180

11.1 The History of Coordination Chemistry180

11.2 Formation of Coordination Compound182

11.3 Nomenclature of Coordination Compounds184

11.4 Structure and Isomerism 185

11.5 Coordination Equilibrium in Solution187

11.6 Valence Bond Theory of Coordination Compounds191

11.7 The Crystal Field Theory194

11.8 The Biological Effects of Coordination Compounds199

Key Words200

Exercises201

Chapter 12 Nonmetals and Semimetals203

12.1 General Concepts203

12.2 Hydrogen203

12.3 Boron204

12.4 The Group ⅣA Elements，the Carbon Group Elements205

12.5 The GroupⅤA Elements，the Nitrogen Group Elements208

12.6 The Group ⅥA Elements，the Oxygen Group Elements211

12.7 The Group ⅦA Elements，the Halogens215

12.8 The Group ⅧA Elements，the Noble Gases218

Key Words218

Exercises219

Chapter 13 Metals 220

13.1 The Group IA Elements220

13.2 The Group ⅡA Elements224

13.3 The Group ⅢA Elements229

13.4 A Survey of Transition Metals232

13.5 Chemistry of Some Transition Metals234

Key Words239

Exercises239

Ⅱ Inorganic Chemical Experiments241

Chapter 1 Basic Techniques of Experimental Chemistry242

1.1 Safety242

1.2 Recording Results243

1.3 Weighing243

1.4 Concerning Liquids244

Chapter 2 Typical Chemical Laboratory Apparatus 252

Chapter 3 Experiments254

3.1 Some Elementary Operation254

3.2 AcidBase Titration256

3.3 Electrolyte Solutions259

3.4 Preparation of Officinal Sodium Chloride and Its Purity Examination 262

3.5 OxidationReduction Reactions267

3.6 Coordination Compounds271

3.7 The Halogens275

3.8 Chromium,Manganese and Iron278

3.9 Copper,Silver,Zinc and Mercury283

3.10 Determination of the Ionization Constant of HAc by pH Meter287

3.11 Preparation of Ammonium Iron（Ⅱ）Sulfate291

3.12 Preparation and Content Determination of Zinc Gluconate294

Appendix296

Reference

《无机化学》针对药学类专业无机化学的双语课程，将无机化学课程的基本内容进行精选,结合国内高校教学实际，删除原版教材中大量的复杂、繁琐及较深奥的部分，力求使之既能体现无机化学课程的专业基础课特色，又可提高学生的英语应用能力。
　　鉴于医药学专业学生理论与实验课程并重的特点，全书包含两大部分：Ⅰ Inorganic Chemistry与Ⅱ Inorganic Chemical Experiments。Part Ⅰ includings thirteen chapters：1 Introduction,2 Structures of Atoms,3 Chemical bonds,4 Thermochemistry,5 Chemical Kinetics,6 Chemical Equilibrium,7 Solutions,8 Solubility Equilibrium,9 AcidBase Equilibria，10 An Introduction to Electrochemistry,11 Chemistry of Coordination Compounds,12 Nonmetals and Semimetals,13 Metals。Part Ⅱ includings three chapters：1 Basic Techniques of Experimental Chemistry,2 Typical Chemical Laboratory Apparatus,3 Experiments。
　　《无机化学》可作为高等院校本科药学及化学类相关专业的无机化学双语教材，也可作为化学专业英语课的教材或参考书。